Saturday, February 14, 2015

The Chemistry in Airbags

Along with seat belts, air bags are one of the main mechanisms that reduce the risk of injury in the unfortunate case of a car accident. Once a car crashes, a sensor detects the strength of the collision and deploys an air bag by reacting three important chemicals, sodium azide (NaN3) potassium nitrate (KNO3), silicon dioxide (SiO2). First, an electric impulse heats sodium azide to up to 300°C, causing it to decompose to nitrogen gas, which fills the airbag, and solid sodium, in the following redox reaction:

2 NaN3 -> 2 Na + 3N2

Since sodium metal is highly reactive, potassium nitrate first reacts to produce potassium oxide and sodium oxide and produce one more unit of nitrogen gas.

2Na + 2KNO3 -> 5Na2O + K2O + N2

Yet, the first period metal oxides are still quite reactive, so they are eliminated by silicon dioxide.

K2O + Na2O + 2SiO2 -> K2SiO3 + Na2SiO3

The end products, potassium silicate (K2SiO3) and silicate glass (Na2SiO3), are much more stable; nitrogen gas inflates the airbag and protects you from the collision.

 How do airbags protect you?

According to Newton's second law:

F= ma = m (dv/dt)

So, if dt increases due to the presence of an air bag, F decreases, reducing the force that is exerted on the body and thus making injuries or death less likely.